论文标题

在强耦合极限的粗粒柜台

Coarse-Grained Counterions in the Strong Coupling Limit

论文作者

Frusawa, Hiroshi

论文摘要

最近在强库仑耦合方案中,最近的蒙特卡洛模拟(A. G. Moreira和R. R. Netz:Eur。Phys。J。E {\ bf 8}(2002)33)表明,与Poisson-Boltzmann不同,与Poisson-Boltzmann不同,奇怪的反静电静电仪与反对互动的次数更大,而不是反对互动,而不是反击的互动,而不是反击互动,而不是反对互动,那么越来越多的静电 - 后者和前者无关紧要。在这里,我们通过数学上操纵强耦合极限来为明显矛盾的静电提供了解释。

Recent Monte Carlo simulations (A. G. Moreira and R. R. Netz: Eur. Phys. J. E {\bf 8} (2002) 33) in the strong Coulomb coupling regime suggest strange counterion electrostatics unlike the Poisson-Boltzmann picture: when counterion-counterion repulsive interactions are much larger than counterion--macroion attraction, the coarse-grained counterion distribution around a macroion is determined only by the latter, and the former is irrelevant. Here, we offer an explanation for the apparently paradoxical electrostatics by mathematically manipulating the strong coupling limit.

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