论文标题
关于Elastocapillary Ridge的奇异性质
On the singular nature of the elastocapillary ridge
论文作者
论文摘要
软接口的功能对于生物学和表面科学中的许多应用至关重要。最近的研究使用液体滴来探测弹性体网络的表面力学。实验表明表面弹性复杂,也称为Shuttleworth效应,在表面张力不是恒定的,而是取决于底物变形。然而,由于奇异的弹性变形,解释仍然存在争议,这些变形正好在液滴拉动网络的位置诱导。在这里,我们揭示了具有各种构成关系的超弹性底物上的弹性毛细血管奇异性的性质。首先,我们使用目标适应有限元模拟来精心解决奇异之处。这证实了先前有争议的Neumann定律的触点定律的普遍有效性,也证实了较大的弹性变形。随后,我们得出了分析描述奇点的非线性弹性的精确解。这些解决方案与数字完全吻合,并表明接触线的拉伸,如先前在实验上测量的,始终指向强大的Shuttleworth效应。最后,使用Noether定理,我们提供了润湿磁滞和类似Eshelby的力之间的定量联系,从而在Shuttleworth效应的情况下提供了完整的软湿润框架。
The functionality of soft interfaces is crucial to many applications in biology and surface science. Recent studies have used liquid drops to probe the surface mechanics of elastomeric networks. Experiments suggest an intricate surface elasticity, also known as the Shuttleworth effect, where surface tension is not constant but depends on substrate deformation. However, interpretations have remained controversial due to singular elastic deformations, induced exactly at the point where the droplet pulls the network. Here we reveal the nature of the elastocapillary singularity on a hyperelastic substrate with various constitutive relations for the interfacial energy. First, we finely resolve the vicinity of the singularity using goal-adaptive finite element simulations. This confirms the universal validity, also at large elastic deformations, of the previously disputed Neumann's law for the contact angles. Subsequently, we derive exact solutions of nonlinear elasticity that describe the singularity analytically. These solutions are in perfect agreement with numerics, and show that the stretch at the contact line, as previously measured experimentally, consistently points to a strong Shuttleworth effect. Finally, using Noether's theorem we provide a quantitative link between wetting hysteresis and Eshelby-like forces, and thereby offer a complete framework for soft wetting in the presence of the Shuttleworth effect.