学术文献库

A comprehensive study has been undertaken on the dimensional swelling of graphene-reinforced elastomers in liquids. Anisotropic swelling was observed for samples reinforced with graphene nanoplatelets (GNPs), induced by the in-plane orientation of the GNPs. Upon the addition of the GNPs, the diameter swelling ratio of the nanocomposites was significantly reduced, whereas the thickness swelling ratio increased and was even greater than that of the unfilled elastomers. The swelling phenomenon has been analyzed in terms of a modification of the Flory-Rhener theory. The newly-derived equations proposed herein, can accurately predict the dependence of dimensional swelling (diameter and thickness) on volume swelling, independent of the type of elastomer and solvent. The anisotropic swelling of the samples was also studied in combination with the evaluation of the tensile properties of the filled elastomers. A novel theory that enables the assessment of volume swelling for GNP-reinforced elastomers, based on the filler geometry and volume fraction has been developed. It was found that the swelling of rubber nanocomposites induces a biaxial constraint from the graphene flakes.