论文标题

Misfit子系统的磁相关性[CA $ _2 $ COO $ _3 $] $ _ {0.62} $ [COO $ _2 $] cobaltate

Magnetic correlations in subsystems of the misfit [Ca$_2$CoO$_3$]$_{0.62}$[CoO$_2$] cobaltate

论文作者

Ahad, Abdul, Gautam, K., Dey, K., Majid, S. S., Rahman, F., Sharma, S. K., Coaquira, J. A. H., da Silva, Ivan, Welter, E., Shukla, D. K.

论文摘要

[ca $ _2 $ coo $ _3 $] $ _ {0.62} $ [COO $ _2 $],一种二维Misticional Misfit Metallic Compound,以其温度的丰富阶段而闻名,即$ $温度旋转状态,$ simer-simperiate温度($ \ sim $ \ sim \ sim \ sim \ sim \ sim \ sim \ sim \)。它进入了T $ _ {MIT} $下方的SDW阶段,该阶段在27 K处长期变长。有关这些阶段中不合适层的独立作用(RockSalt/ca $ _2 $ _3 $ _3 $ _3 $ _3 $ _3 $ \&triangular/coo $ _2 $)在这些阶段中很少。通过结合一组互补的宏观(DC磁化和电阻率)以及微观(中子衍射和X射线吸收良好的结构光谱谱图)测量纯度(CCO),在CCO(CCO1)中取代的TB(CCO1)(CCO1)中的TB(CCO1)(CCO1)(CCO1),这两个磁性相关性,这两个磁性相关性,这是该磁性不合适的磁相关性。发现CCO表现出玻璃性以及交换偏差(EB)效果,而CCO1则表现出玻璃性,尽管它显示出较弱的EB效应。通过结合扩展X射线吸收精细结构(EXAFS)光谱和中子衍射结果的局部结构研究,我们确认SDW在COO $ _2 $ layer中出现。我们的结果表明,与岩石层相关的磁晶各向异性充当固定的来源,这是负责EB效应的。 CA $ _2 $ COO $ _3 $中的铁磁簇影响COO $ _2 $的SDW,并最终出现了玻璃。

[Ca$_2$CoO$_3$]$_{0.62}$[CoO$_2$], a two dimensional misfit metallic compound, is famous for its rich phases accessed by temperature, $i.e.$ high temperature spin-state transition, metal-insulator transition (MIT) at intermediate temperature ($\sim$ 100 K) and low temperature spin density wave (SDW). It enters into SDW phase below T$_{MIT}$ which becomes long range at 27 K. Information on the independent role of misfit layers (rocksalt/Ca$_2$CoO$_3$ \& triangular/CoO$_2$) in these phases is scarce. By combining a set of complementary macroscopic (DC magnetization and resistivity) and microscopic (neutron diffraction and X-ray absorption fine structure spectroscopy) measurements on pure (CCO) and Tb substituted in the rocksalt layer of CCO (CCO1), magnetic correlations in both subsystems of this misfit compound are unraveled. CCO is found to exhibit glassiness, as well as exchange bias (EB) effects, while CCO1 does not exhibit glassiness, albeit it shows weaker EB effect. By combining local structure investigations from extended X-ray absorption fine structure (EXAFS) spectroscopy and neutron diffraction results on CCO, we confirm that the SDW arises in the CoO$_2$ layer. Our results show that the magnetocrystalline anisotropy associated with the rocksalt layer acts as a source of pinning, which is responsible for EB effect. Ferromagnetic clusters in the Ca$_2$CoO$_3$ affects SDW in CoO$_2$ and ultimately glassiness arises.

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