学术文献库

Directing the propagation of near-infrared radiation is a major concern in improving the efficiency of solar cells and thermal insulators. A facile approach to scatter light in the near-infrared region without excessive heating is to embed compact layers with semiconductor particles. The directional scattering by semiconductor@oxide (core@shell) spherical particles (containing Si, InP, TiO$_2$, SiO$_2$, or ZrO$_2$) with a total radius varying from 0.1 to 4.0 μm and in an insulating medium at low volume fraction is investigated using Lorenz-Mie theory and multiscale modelling. The optical response of each layers is calculated under irradiation by the sun or a blackbody emitter at 1180 K. Reflectance efficiency factors of up to 83.7% and 63.9% are achieved for near-infrared solar and blackbody radiation in 200 μm thick compact layers with only 1% volume fraction of bare Si particles with a radius of 0.23 μm and 0.50 μm, respectively. The maximum solar and blackbody efficiency factors of layers containing InP particles was slightly less (80.2% and 60.7% for bare particles with a radius of 0.25 μm and 0.60 μm, respectively). The addition of an oxide coating modifies the surrounding dielectric environment, which improves the solar reflectance efficiency factor to over 90% provided it matches the scattering mode energies with the incident spectral density. The layers are spectrally-sensitive and can be applied as a back or front reflector for solar devices, high temperature thermal insulators, and optical filters in Gradient Heat Flux Sensors for fire safety applications.