论文标题

异质弹性:玻色子峰的故事

Heterogeneous Elasticity: The tale of the boson peak

论文作者

Schirmacher, Walter, Ruocco, Giancarlo

论文摘要

玻璃的振动异常,尤其是玻色子峰,从异质弹性的角度来解决,即弹性常数的空间波动是由无定形材料的结构障碍引起的。 在本文文章的第一部分中,在相同条件下,在无序环境中扩散运动与振动运动的标量简化之间的数学类比已得到重新置。我们证明了疾病引起的扩散的长时间尾巴对应于振动系统中的瑞利散射法,并且从正常到异常扩散到异常扩散的交叉对应于玻色峰。一旦无序诱导的自我能量超过频率独立的扩散率/弹性,就会出现异常运动。对于此模型,将变异方案汇总用于得出两种均值障碍理论,即自一致的天生近似(SCBA)和相干势力近似(CPA)。前者适用于波动较弱且高斯,后者适用于更强和非高斯波动。 在第二部分中,在SCBA和CPA中提出并解决了为标量模型引入的异质弹性的媒介理论。两种方法都预测并解释了玻色峰和相关的异常,即声相速度的下降,以及在玻色峰以下的声学衰减的特征强大增加。给出了状态密度和非弹性拉曼,中子和X射线散射定律的显式表达。讨论了解释玻色峰异常的最新冲突方法。

The vibrational anomalies of glasses, in particular the boson peak, are addressed from the standpoint of heterogeneous elasticity, namely the spatial fluctuations of elastic constants caused by the structural disorder of the amorphous materials. In the first part of this review article a mathematical analogy between diffusive motion in a disordered environment and a scalar simplification of vibrational motion under the same condition is emploited. We demonstrate that the disorder-induced long-time tails of diffusion correspond to the Rayleigh scattering law in the vibrational system and that the cross-over from normal to anomalous diffusion corresponds to the boson peak. The anomalous motion arises as soon as the disorder-induced self-energy exceeds the frequency-independent diffusivity/elasticity. For this model a variational scheme is emploited for deriving two mean-field theories of disorder, the self-consistent Born approximation (SCBA) and coherent-potential approximation (CPA). The former applies if the fluctuations are weak and Gaussian, the latter applies for stronger and non-Gaussian fluctuations. In the second part the vectorial theory of heterogenous elasticity is presented and solved in SCBA and CPA, introduced for the scalar model. Both approaches predict and explain the boson-peak and the associated anomalies, namely a dip in the acoustic phase velocity and a characteristic strong increase of the acoustic attenuation below the boson peak. Explicit expressions for the density of states and the inelastic Raman, neutron and X-ray scattering laws are given. Recent conflicting ways of explaining the boson-peak anomalies are discussed.

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