论文标题

原子配置控制的光电流在范德华同源物中

Atomic configuration controlled photocurrent in van der Waals homostructures

论文作者

Xiong, Ying, Shi, Li-kun, Song, Justin C. W.

论文摘要

P-N连接处的常规光电取决于宏观内置场,通常对晶体原子构型的微观细节不敏感。在这里,我们演示了原子构型如何控制范德华(VDW)材料中的光电流。特别是,我们发现大量的移位光电(SPC)可以显示丰富的(原子)构型依赖性现象学,范围从VDW同源物(例如AB VS VS VS BA堆叠)中的不同堆叠布置的对比SPC电流到与结晶轴相位的SPC的强光相依赖性。引人注目的是,我们发现VDW同义结构中的SPC可以通过适度的应变指向,在未脱光化的光照射下产生相当大的光电流幅度,即使在没有P-N连接的情况下也表现出来。这些表明,SPC与Bloch波形如何嵌入真实空间密切相关,并在VDW材料中启用了晶格规模的新型宏观运输探针(PhotoCurrent)。

Conventional photocurrents at a p-n junction depend on macroscopic built-in fields and are typically insensitive to the microscopic details of a crystal's atomic configuration. Here we demonstrate how atomic configuration can control photocurrent in van der Waals (vdW) materials. In particular, we find bulk shift photocurrents (SPC) can display a rich (atomic) configuration dependent phenomenology that range from contrasting SPC currents for different stacking arrangements in a vdW homostructure (e.g., AB vs BA stacking) to a strong light polarization dependence for SPC that align with crystallographic axes. Strikingly, we find that SPC in vdW homostructures can be directed by modest strain, yielding sizeable photocurrent magnitudes under unpolarized light irradiation and manifesting even in the absence of p-n junctions. These demonstrate that SPC are intimately linked to how the Bloch wavefunctions are embedded in real space, and enables a new macroscopic transport probe (photocurrent) of lattice-scale registration in vdW materials.

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