论文标题

纳米颗粒和聚集体附近光学手性的方向平均

Orientation Averaging of Optical Chirality Near Nanoparticles and Aggregates

论文作者

Fazel-Najafabadi, Atefeh, Schuster, Sebastian, Auguié, Baptiste

论文摘要

人工纳米结构能够对纳米级电磁场的精细控制,最近可能扩展到极化光和手性物质之间的相互作用。这种相互作用的理论描述及其在精心光谱镜的优化结构设计中的应用,为纳米镜中使用的常见工具带来了新的挑战。特别是,手势效应通常取决于散射器和入射光的相对方向,但是许多实验是用随机取向的散射器进行的,分散在溶液中。我们在存在纳米粒子聚集体的情况下为电磁场的方向平均局部光学手性提供了新的表达式。这是使用叠加t -matrix框架实现的,非常适合在光散射问题中推导有效的方向平均公式。我们的结果应用于一些模型示例,并说明了纳米结构周围的手性水平分布的几个非直觉方面。对于旨在增强手势光谱镜的纳米颗粒组件的研究以及在平均光学手学程度的数值计算中,对纳米颗粒组件的研究将引起重大关注。

Artificial nanostructures enable fine control of electromagnetic fields at the nanoscale, a possibility that has recently been extended to the interaction between polarised light and chiral matter. The theoretical description of such interactions, and its application to the design of optimised structures for chiroptical spectroscopies, brings new challenges to the common set of tools used in nano-optics. In particular, chiroptical effects often depend crucially on the relative orientation of the scatterer and the incident light, but many experiments are performed with randomly-oriented scatterers, dispersed in a solution. We derive new expressions for the orientation-averaged local degree of optical chirality of the electromagnetic field in the presence of a nanoparticle aggregate. This is achieved using the superposition T -matrix framework, ideally suited for the derivation of efficient orientation-averaging formulas in light scattering problems. Our results are applied to a few model examples, and illustrate several non-intuitive aspects in the distribution of orientation-averaged degree of chirality around nanostructures. The results will be of significant interest for the study of nanoparticle assemblies designed to enhance chiroptical spectroscopies, and where the numerically-efficient computation of the averaged degree of optical chirality enables a more comprehensive exploration of the many possible nanostructures.

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