论文标题

krypton中的皮秒两光子吸收激光诱导的荧光(ps-talif):光离子化对荧光状态kr 5p的密度耗竭的作用

Picosecond two-photon absorption laser induced fluorescence (ps-TALIF) in krypton: the role of photoionization on the density depletion of the fluorescing state Kr 5p'[3/2]$_2$

论文作者

Gazeli, K., Aubert, X, Prasanna, S, Duluard, C., Lombardi, G., Hassouni, K.

论文摘要

本研究的重点是在可变压力(0.1-10 MBAR)下使用Picsecond(PS)Talif技术在K Krypton(KR)中的应用。激光强度(I,单位W.CM $^{ - 2} $)调节1至480 mw.cm $^{ - 2} $,以及KR 5P'[3/2] $ _ 2 $ _ 2 $ _ 2 $ the ulororescunited状态(通过painioniation(PIN)进行液体(PIN)和添加刺激的刺激(ase)的耗竭(ase)的耗尽。这是通过将塔里夫实验与简单的0D数值模型相结合来完成的。我们证明,对于3 MBAR和15 <$ \ le $ 480 mw.cm $^{ - 2} $的气压,获得了饱和的荧光信号,这在很大程度上归因于销钉,即可忽略不计。此外,由于通过PIN生产带电物种的产生,记录了两光子吸收系(即4p $^6 $ $^1 $^1 $ s0 $ \至$ 5p'[3/2] $ _ 2 $)。但是,对于I $ \ le $ 15 mw.cm $^{ - 2} $,销钉明显有限,吸收线明显缩小,并且塔利夫信号强度的二次依赖性与激光器能量相比。因此,在这种情况下,使用5p'[3/2] $ _ 2 \至$ 5S [3/2] $ _ 1 $荧光通道的研究的KR Talif方案可用于PSALIF实验中。这些结果对于基础研究引起了人们的关注,因为在KR中进行的大多数PS-TALIF研究都没有详细研究PIN和ASE在KR 5P'[3/3/2] $ _ 2 $状态密度的耗竭中的作用。此外,这项工作有助于开发PS-TALIF,以确定等离子体中H和N原子的绝对密度和淬灭系数。这在许多基于等离子体的应用中很有用(例如薄膜合成,生物医学处理,等离子体辅助燃烧,...),对于反应性原子的密度/动力学的知识至关重要。

The present study focuses on the application of a picosecond (ps) TALIF technique in krypton (Kr) at variable pressure (0.1-10 mbar). The laser intensity (I, units W.cm$^{-2}$) is tuned between 1 and 480 MW.cm$^{-2}$, and the depletion of the density of the Kr 5p'[3/2]$_2$ fluorescing state through photoionization (PIN) and amplified stimulated emission (ASE) is investigated. This is done by combining TALIF experiments with a simple 0D numerical model. We demonstrate that for a gas pressure of 3 mbar and 15 < $\le$ 480 MW.cm$^{-2}$, a saturated fluorescence signal is obtained, which is largely attributed to PIN, ASE being negligible. Also, a broadening of the two-photon absorption line (i.e. 4p$^6$ $^1$S0$\to$5p'[3/2]$_2$) is recorded due to the production of charged species through PIN, inducing a Stark effect. For I$\le$15 MW.cm$^{-2}$, though, PIN is significantly limited, the absorption line is noticeably narrowed, and the quadratic dependence of the TALIF signal intensity versus the laser energy is obtained. Thus, in this case, the investigated Kr TALIF scheme, using the 5p'[3/2]$_2\to$5s[3/2]$_1$ fluorescence channel, can be used for calibration purposes in ps-TALIF experiments. These results are of interest for fundamental research since most ps-TALIF studies performed in Kr do not investigate in detail the role of PIN and ASE on the depletion of the Kr 5p'[3/2]$_2$ state density. Moreover, this work contributes to the development of ps-TALIF for determining absolute densities and quenching coefficients of H and N atoms in plasmas. This is useful in numerous plasma-based applications (e.g. thin film synthesis, biomedical treatments, plasma-assisted combustion, ...), for which the knowledge of the density/kinetics of reactive atoms is essential.

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