论文标题
磷分子朝向原始类似物的第一张图像
First images of phosphorus molecules towards a proto-Solar analog
论文作者
论文摘要
尽管磷在陆生生物化学中的核心作用,但磷酸和行星形成区域中磷的化学尚不清楚。我们将PO和PN对I类Protostar B1-A的ALMA带3和4观察结果表示,这代表了磷载体对太阳能型星形成区域的第一个空间分辨观测值。磷分子从两个不同的团块中散发出来,这与原始流出(由SIO追踪)的区域一致,与密集的气体(由CCS追踪)相互作用。因此,气相磷似乎源于密集的星际团块的震动。基于观察到的发射模式,PO和PN似乎是固体磷载体的子产物,在冰与硅酸盐之间具有中间波动率。因此,星际冲击可能在将半浪费性磷转换为更挥发性形式的形式中,在掺入彗星冰中。实际上,(PO+PN)/CH3OH比在B1-A和67p中相似,这意味着可比的挥发性磷储存库。 PO/PN比率在B1-A的〜1-8范围内。北部发射团的PO/PN比较低,而13CH3OH的发射较低,而Southern Clump的发射率较低,这表明这两个位置在两个位置上具有独特的休克物理和化学性质。需要对P载体朝其他来源进行解决的观察结果,以更好地了解哪些是在Protostellar环境中调节PO/PN比的这种变化的。
The chemistry of phosphorus in star- and planet-forming regions is poorly understood, despite the central role of phosphorus in terrestrial biochemistry. We present ALMA Band 3 and 4 observations of PO and PN towards the Class I protostar B1-a, representing the first spatially resolved observations of phosphorus carriers towards a Solar-type star forming region. The phosphorus molecules emit from two distinct clumps, which coincide with regions where the protostellar outflow (traced by SiO) interacts with a filament of dense gas (traced by CCS). Thus, the gas-phase phosphorus seems to originate from the shocking of dense interstellar clumps. Based on the observed emission patterns, PO and PN appear to be daughter products of a solid phosphorus carrier with an intermediate volatility between ices and silicate grains. Interstellar shocks may therefore play an important role in converting semi-refractory phosphorus to a more volatile form prior to incorporation into cometary ices. Indeed, the (PO+PN)/CH3OH ratio is similar in B1-a and comet 67P, implying a comparable reservoir of volatile phosphorus. The PO/PN ratio ranges from ~1-8 across B1-a. The northern emission clump exhibits a lower PO/PN ratio and weaker 13CH3OH emission than southern clump, indicating distinct shock physics and chemistry at the two positions. Resolved observations of P carriers towards additional sources are needed to better understand what regulates such variations in the PO/PN ratio in protostellar environments.