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Internet-of-vehicle (IoV) is a general concept referring to, e.g., autonomous drive based vehicle-to-everything (V2X) communications or moving relays. Here, high rate and reliability demands call for advanced multi-antenna techniques and millimeter-wave (mmw) based communications. However, the sensitivity of the mmw signals to blockage may limit the system performance, especially in highways/rural areas with limited building reflectors/base station deployments and high-speed devices. To avoid the blockage, various techniques have been proposed among which reconfigurable intelligent surface (RIS) is a candidate. RIS, however, has been mainly of interest in stationary/low mobility scenarios, due to the associated channel state information acquisition and beam management overhead as well as imperfect reflection. In this article, we study the potentials and challenges of RIS-assisted dynamic blockage avoidance in IoV networks. Particularly, by designing region-based RIS pre-selection as well as blockage prediction schemes, we show that RIS-assisted communication has the potential to boost the performance of IoV networks. However, there are still issues to be solved before RIS can be practically deployed in IoV networks.