论文标题
一个简单的模型,用于超流体中分子的高旋转激发
A simple model for high rotational excitations of molecules in a superfluid
论文作者
论文摘要
我们提出了一个简单的量子机械模型,该模型描述了超氟氦纳米光中分子的激发旋转态,如最近在非绝热分子比对实验中所研究的[Cherepanov等,Phys。 Rev. A 104,L061303(2021)]。我们表明,浸入超氟的线性分子可以看作是有效的对称顶部,类似于自由基的旋转结构,例如OH或NO,但具有超氟的角动量,在自由分子中具有电子角动量的作用。该模型允许评估广泛物种的有效旋转和离心失真常数,并解释超富集$^4 $ HE在多体波函数结构方面的光和重分子之间的交叉。最重要的是,简单的理论允许回答问题,即当分子的旋转角动量增加超过红外光谱可访问的最低激发态时会发生什么。可以通过分析简单的2x2矩阵来获得上述一些见解。
We present a simple quantum mechanical model describing excited rotational states of molecules in superfluid helium nanodroplets, as recently studied in non-adiabatic molecular alignment experiments [Cherepanov et al., Phys. Rev. A 104, L061303 (2021)]. We show that a linear molecule immersed in a superfluid can be seen as an effective symmetric top, similar to the rotational structure of radicals, such as OH or NO, but with the angular momentum of the superfluid playing the role of the electronic angular momentum in free molecules. The model allows to evaluate the effective rotational and centrifugal distortion constants for a broad range of species and to explain the crossover between light and heavy molecules in superfluid $^4$He in terms of the many-body wavefunction structure. Most important, the simple theory allows to answer the question as to what happens when the rotational angular momentum of the molecule increases beyond the lowest excited states accessible by infrared spectroscopy. Some of the above mentioned insights can be acquired by analyzing a simple 2x2 matrix.