论文标题
地球氮的起源:原始还是生物地球化学的早期循环?
The origin of Earth's mantle nitrogen: primordial or early biogeochemical cycling?
论文作者
论文摘要
地球的地幔氮(N)含量与在其富含N的大气中发现的含量相当。已提出地幔n是原始的或以后的俯冲来源,但尚未阐明其起源。在这里,我们使用氩(AR)和N同位素作为示踪剂,在地球形成之后的岩浆海洋阶段进行了N分区,并在地球历史上进行了随后的循环。受AR约束的分区模型表明,由于N在地球物理和地球化学研究支持的氧化条件下,在岩浆中N溶解度的低溶解性和矿物质的低分配系数,因此只有约10%的总N含量被困在固化地幔中。原始起源的一种可能的解决方案是,在岩浆海洋凝固时,地球的氮是n的10倍。我们表明,在积聚后期,可以通过撞击侵蚀去除多余的n。受N同位素约束的循环模型表明,如果早期地球上的沉积N埋葬率与现代地球相媲美,地幔N可以起源于有效的N俯冲。如此高的n埋葬率需要生物加工。最后,我们的模型提供了一种方法,可以通过对表面和地幔N同位素记录的未来分析来区分两个可能的起源。
Earth's mantle nitrogen (N) content is comparable to that found in its N-rich atmosphere. Mantle N has been proposed to be primordial or sourced by later subduction, yet its origin has not been elucidated. Here we model N partitioning during the magma ocean stage following planet formation and the subsequent cycling between the surface and mantle over Earth history using argon (Ar) and N isotopes as tracers. The partitioning model, constrained by Ar, shows that only about 10% of the total N content can be trapped in the solidified mantle due to N's low solubility in magma and low partitioning coefficients in minerals in oxidized conditions supported from geophysical and geochemical studies. A possible solution for the primordial origin is that Earth had about 10 times more N at the time of magma ocean solidification. We show that the excess N could be removed by impact erosion during late accretion. The cycling model, constrained by N isotopes, shows that mantle N can originate from efficient N subduction, if the sedimentary N burial rate on early Earth is comparable to that of modern Earth. Such a high N burial rate requires biotic processing. Finally, our model provides a methodology to distinguish the two possible origins with future analysis of the surface and mantle N isotope record.