论文标题
束缚纳米骨的临界剥离
Critical Peeling of Tethered Nanoribbons
论文作者
论文摘要
在工程和宏观摩擦学中,固定的吸附膜的剥离是一个众所周知的问题。在经典的设置中,以一个极端的形式捡起并取下剥离力的结果,这是拾取角度的降低功能。由于抬起一端,分离的前部缩回以满足固定的尾巴。在纳米级,在金上剥离石墨烯纳米纤维(GNR)在金上,如原子力显微镜所实现的那样,出现了有趣的情况。纳米化的系统显示出恒定的稳定剥离状态,其中尖端提起H不会产生带状脱离点的缩回,并且只是自由尾部端的进步H。这与经典案例相反,在经典情况下,分离点缩回,尾部末端保持静止。在这里,我们通过分析建模和数值模拟来表征第三个实验相关的设置,其中纳米甲(尽管在结构上是润滑的,但没有自由移动的尾部端,相反,它是绑扎的。令人惊讶的是,新型的非平凡缩放指数似乎调节了剥离的演变。随着脱离的前部缩回和束缚的尾巴被拉伸,H的功率定律表征了粘附长度的缩小剥离力和剥离角的生长。这些指数在最终总脱离之前是一个临界点,整个丝带最终悬挂在尖端和绑扎弹簧之间。这些分析预测通过现实的MD模拟证实,保留了完整的原子描述,也证实了它们在有限的实验温度下的生存。
The peeling of an immobile adsorbed membrane is a well known problem in engineering and macroscopic tribology. In the classic setup, picking up at one extreme and pulling off results in a peeling force that is a decreasing function of the pickup angle. As one end is lifted, the detachment front retracts to meet the immobile tail. At the nanoscale, interesting situations arise with the peeling of graphene nanoribbons (GNRs) on gold, as realized, e.g., by atomic force microscopy. The nanosized system shows a constant-force steady peeling regime, where the tip lifting h produces no retraction of the ribbon detachment point, and just an advancement h of the free tail end. This is opposite to the classic case, where the detachment point retracts and the tail end stands still. Here we characterise, by analytical modeling and numerical simulations, a third, experimentally relevant, setup where the nanoribbon, albeit structurally lubric, does not have a freely moving tail end, which is instead elastically tethered. Surprisingly, novel nontrivial scaling exponents appear that regulate the peeling evolution. As the detachment front retracts and the tethered tail is stretched, power laws of h characterize the shrinking of the adhered length the growth of peeling force and the peeling angle. These exponents precede the final total detachment as a critical point, where the entire ribbon eventually hangs suspended between the tip and tethering spring. These analytical predictions are confirmed by realistic MD simulations, retaining the full atomistic description, also confirming their survival at finite experimental temperatures.