论文标题

有限控制的最佳方案任意远离均衡

Limited-control optimal protocols arbitrarily far from equilibrium

论文作者

Zhong, Adrianne, DeWeese, Michael R.

论文摘要

最近的研究探索了随机热力学系统的有限时间耗散协议,当被授予完全外部控制以驱动系统时,任意驱动的随机热力学系统驱动了远离平衡。但是,在模拟和实验环境中,系统通常只能以有限的自由度来控制。在这里,除了先前研究中使用的慢速和快速驾驶近似值之外,我们为这种未开发的有限控制设置获得了确切的有限时间最佳协议。通过使用确定性的Fokker-Planck概率密度时间演变,我们可以以最佳控制理论问题的标准形式将工作最小的协议问题构架。我们证明,找到确切的最佳协议等于解决哈密顿局部偏微分方程系统,在许多情况下,该方程在许多情况下承认有效计算的数值解决方案。在此框架内,我们为谐波电位的最佳控制重现了分析结果,并为两个非谐波示例设计了新颖的最佳方案:改变四分之一电位的刚度,并线性偏向双孔电位。我们确认,这些最佳协议的表现优于通过以前的方法产生的其他协议,在某些情况下大量量。我们发现,对于线性偏见的双孔问题,最佳协议下的平均位置在接近恒定的速度下行驶。令人惊讶的是,对于特定时间表和屏障高度制度,最佳协议在时间上也是非单调的。

Recent studies have explored finite-time dissipation-minimizing protocols for stochastic thermodynamic systems driven arbitrarily far from equilibrium, when granted full external control to drive the system. However, in both simulation and experimental contexts, systems often may only be controlled with a limited set of degrees of freedom. Here, going beyond slow- and fast-driving approximations employed in previous studies, we obtain exact finite-time optimal protocols for this unexplored limited-control setting. By working with deterministic Fokker-Planck probability density time evolution, we can frame the work-minimizing protocol problem in the standard form of an optimal control theory problem. We demonstrate that finding the exact optimal protocol is equivalent to solving a system of Hamiltonian partial differential equations, which in many cases admit efficiently calculatable numerical solutions. Within this framework, we reproduce analytical results for the optimal control of harmonic potentials, and numerically devise novel optimal protocols for two anharmonic examples: varying the stiffness of a quartic potential, and linearly biasing a double-well potential. We confirm that these optimal protocols outperform other protocols produced through previous methods, in some cases by a substantial amount. We find that for the linearly biased double-well problem, the mean position under the optimal protocol travels at a near-constant velocity. Surprisingly, for a certain timescale and barrier height regime, the optimal protocol is also non-monotonic in time.

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