论文标题
结构化液体的全面连续理论
A comprehensive continuum theory of structured liquids
论文作者
论文摘要
我们开发了一个综合的连续模型，能够处理液态介电中的静电和结构相互作用。从电荷密度和极化方面的两阶参数描述开始，我们得出了一个概括以前理论的现场理论模型。我们的理论明确包括大部分液体中的静电和结构相互作用，并允许在DRUDE模型中产生极化电荷。特别是，我们对边界条件进行了详细描述，其中包括电荷调节机理和表面极化。解决我们模型的鞍点方程的一般特征是阐明的，并概述了未来的应用以预测和验证实验结果。
We develop a comprehensive continuum model capable of treating both electrostatic and structural interactions in liquid dielectrics. Starting from a two-order parameter description in terms of charge density and polarization, we derive a field-theoretic model generalizing previous theories. Our theory explicitly includes electrostatic and structural interactions in the bulk of the liquid and allows for polarization charges within a Drude model. In particular, we develop a detailed description of the boundary conditions which include the charge regulation mechanism and surface polarization. The general features for solving the saddle-point equations of our model are elucidated and future applications to predict and validate experimental results are outlined.
