论文标题

超薄AG和AU膜的厚度依赖性阻尼常数和等离子体频率的测定:纳米级介电函数

Determination of Thickness-dependent Damping Constant and Plasma Frequency for Ultrathin Ag and Au Films: Nanoscale Dielectric Function

论文作者

Herrera, Luis J. Mendoza, Tebaldi, Myrian C., Scaffardi, Lucía B., Schinca, Daniel C.

论文摘要

在光电子,高分辨率显微镜,成像和感测等中,对等离子体2D纳米材料的发展的兴趣越来越大。随着超薄贵金属膜沉积的当前能力降低到厚度的少数单层,需要对厚度依赖性复合介电介质函数进行分析表达,以预测任意厚度的光学特性。由于它们的影响会影响单独的波长范围,因此独立处理了对电介质功能的自由电子贡献。前者是在DRUDE模型框架内进行的,用于大波长,具有适当解决的阻尼常数和等离子体频率参数以考虑厚度依赖性。采用我们先前开发的方法,我们基于Ag和Au薄膜的折射率实验值确定了特定膜厚度的这些参数。分别拟合这些参数中的每个参数使我们能够找到它们对任意膜厚度的依赖性的分析表达,从而找到了自由电子贡献。关于结合电子,可以看出,对于所有分析的厚度,其对小波长的贡献都是相同的,并且可以将其设置为等于块状结合的贡献。考虑到所有这些事实,可以根据批量介电函数以及矫正膜厚度依赖性术语来分析复杂的介电函数。特别是,阻尼常数的拟合过程使我们能够确定银和金薄膜的电子散射主要是扩散的(无弹性)。还表明,根据理论研究,血浆频率显示出随着膜厚度降低而形成的红移。

There is an ever increasing interest in the development of plasmonic 2D nanomaterials, with widespread applications in optoelectronics, high resolution microscopy, imaging and sensing, among others. With the current ability of ultrathin noble metal film deposition down to a few monolayers in thickness, there is a need for an analytical expression of the thickness dependent complex dielectric function for predicting optical properties for arbitrary thicknesses. The free and bound electron contributions to the dielectric function are dealt with independently, since their influences affect separate wavelengths ranges. The former is dealt within the Drude model framework for large wavelengths with appropriately addressed damping constant and plasma frequency parameters to account for thickness dependence. Applying our previously developed method, we determine these parameters for specific film thicknesses, based on refractive index experimental values for Ag and Au thin films. Fitting separately each one of these parameters allowed us to find an analytical expression for their dependence on arbitrary film thickness and consequently for the free electron contribution. Concerning bound electrons, it is seen that its contribution for small wavelengths is the same for all analyzed thicknesses and may be set equal to the bulk bound contribution. Taking all these facts into account, the complex dielectric function can be rewritten analytically, in terms of the bulk dielectric function plus corrective film thickness dependent terms. In particular, the fitting process for the damping constant allows us to determine that the electron scattering at the film boundary is mainly diffusive (inelastic) for both silver and gold thin films. It is also shown that, in accordance with theoretical studies, plasma frequency shows a red shift as the film thickness decreases.

扫码加入交流群

加入微信交流群

微信交流群二维码

扫码加入学术交流群,获取更多资源