论文标题

α-Ti中Al和Sn的晶体学排序

Crystallographic ordering of Al and Sn in α-Ti

论文作者

Worsnop, Felicity F., Lea, Susannah L. M., Ilavsky, Jan, Rugg, David, Dye, David

论文摘要

越来越多的关注正在向$α$$ _ 2 $ ti $ _3 $ _3 $ _3 $ _3 $(Al,sn)降水,这是由于其对滑动带形成,本地化的影响以及对喷气发动机钛对疲劳性能的影响,钛合金的$α$相位。但是,在TEM,中子衍射或原子探针分析中,很难观察到$α$$ _ 2 $降水的早期阶段。在这里,小角度X射线散射用于重新检查二进制Ti-Al和Ti-Sn合金中的相边界,其含量约为500 ppmw o。发现文献中的相位界限大约是正确的,在6.2 wt。%Al和16.9wt。%sn中,这有帮助Al as a a a a a a s a a s sn sn sn sn sn sn sn sn sn的使用效果,并效仿了sn sn sn的稳定性。但是,一旦考虑到$α$+$β$合金中的o含量和相位分区,这意味着应大大降低$ _ {eq} $限制,以使未来的合金设计限制。

Increasing attention is being paid to $α$$_2$ Ti$_3$(Al,Sn) precipitation from the $α$ phase of titanium alloys owing to its effect on slip band formation, localisation and the implications for fatigue performance in jet engine titanium. However, the early stages of $α$$_2$ precipitation have historically been difficult to observe in TEM, neutron diffraction or atom probe analysis. Here, small angle X-ray scattering is used to reexamine the phase boundary in binary Ti-Al and Ti-Sn alloys with around 500 ppmw O. It is found that the phase boundaries in the literature are approximately correct, at 6.2 wt.% Al and 16.9 wt.% Sn, and that this favours the use of Al as a solid solution strengthener over Sn for ambient temperature applications. However, once O content and phase partitioning in $α$+$β$ alloys are taken into account, this implies that Al$_{eq}$ limits for future alloy design of critical rotating parts should be lowered substantially.

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