论文标题
等温过程等绝热过程
Adiabatic processes like isothermal processes
论文作者
论文摘要
这项工作的目的是表明绝热过程可能与等温过程非常相似。首先,我们表明,线性响应理论与热分离系统的热力学第二定律的兼容性标准与执行等温过程的系统相同。在这种结果的驱动下,我们探讨了时间平均过剩工作的热力学后果,观察到了遵守热力学第二定律的热隔离系统的明确定义的松弛时间出乎意料的存在。通过认识到这种系统在通常的意义上是随机放松时间,这可以通过``平均''来``平均''来证明这一点是合理的。这样的过程与等温过程中发生的过程非常相似,在放松函数上必须进行随机平均值才能具有明确定义的放松时间。最后,我们从这种新的角度分析了Landau-Zener模型,讨论了从线性响应理论中构建缓慢变化的过程,并观察到非单调和快速方案的负熵产生速率。
The objective of this work is to show that adiabatic processes can be very similar to isothermal ones. First, we show that the criteria for the compatibility of linear-response theory with the Second Law of Thermodynamics for thermally isolated systems are the same as those for systems performing isothermal processes. Motivated by such a result, we explore the thermodynamic consequences of the time-average excess work, observing an unexpected existence of a well-defined relaxation time for thermally isolated systems that obeys the Second Law of Thermodynamics. This is justified by recognizing that such systems, in the usual sense, present random relaxation time, which can be ``averaged'' by taking the time average of the relaxation function. Such a procedure is very similar to what happens in isothermal processes, where a stochastic average must be done on the relaxation function to have a well-defined relaxation time. In the end, we analyze the Landau-Zener model from this new point of view, discussing the construction of slowly-varying processes from linear-response theory and observing negative entropy production rates for non-monotonic and rapid protocols.