学术文献库

Polymer syntactic foams are transforming materials that will shape the future of next-generation aerospace and marine structures. When manufactured using traditional processes, like compression molding, syntactic foams consist of a solid continuous polymer matrix reinforced with stiff hollow particles. However, polymer matrix segregation can be achieved during the selective laser sintering process with thermoplastic polyurethane (TPU). It is uncertain what role hollow particles play in forming this matrix segregation and its impact on the corresponding mechanical properties of syntactic foams. We show that the size of the hollow particles controls the internal microscale morphology of matrix segregation, leading to counter-intuitive macroscale mechanical responses. Particles with diameters greater than the gaps between the cell walls of the segregated matrix get lodged between and in the walls, bridging the gaps in the segregated matrix and increasing the stiffness of syntactic foams. In contrast, particles with smaller diameters with higher particle crushing strength get lodged only inside the cell walls of the segregated matrix, resulting in higher densification stresses (energy absorption). We show that stiffness and densification can be tuned while enabling lightweight syntactic foams. These novel discoveries will aid in facilitating functional and lightweight syntactic foams for cores in sandwich structures.