论文标题

自我驱动玻璃板的配置熵

Configurational Entropy of Self Propelled Glass Formers

论文作者

N, Sachin C, Joy, Ashwin

论文摘要

配置熵是一种必不可少的工具,可描述玻璃过渡附近的超冷液体。它的计算需要在势能景观中枚举盆地,并在可用时揭示与液体的松弛时间的直接连接。尽管有几份关于被动液体中构型熵的测量的报道,但几乎没有理解其在活性液体中的作用,这些液体的作用倾向于在低温下进行玻璃过渡。在本文中,我们报告了模型玻璃中的构型熵的仔细计算。我们表明,与被动液体不同,这些自propelled液体中对玻璃熵的非谐贡献与谐波贡献的顺序相同,因此必须包括在构型熵的计算中。我们提取的配置熵与随机一阶过渡理论预测的广义Adam-Gibbs关系非常吻合,这使我们能够在这些活性系统中推断出构型熵与点点长度尺度之间的缩放关系。我们的发现在常规活动系统中可能具有很大的效用,例如自propelled颗粒,Janus颗粒和密集的细菌悬浮液,以提及一些。

The configurational entropy is an indispensable tool to describe super-cooled liquids near the glass transition. Its calculation requires the enumeration of the basins in the potential energy landscape and when available, it reveals a direct connection with the relaxation time of the liquid. While there are several reports on the measurement of configurational entropy in passive liquids, very little is understood about its role in active liquids which have a propensity to undergo a glass transition at low temperatures. In this paper, we report a careful calculation of the configurational entropy in a model glass former where the constituent units are self propelled. We show that unlike passive liquids, the anharmonic contribution to the glass entropy in these self-propelled liquids can be of the same order as the harmonic contribution, and therefore must be included in the calculation of the configurational entropy. Our extracted configurational entropy is in good agreement with the generalized Adam-Gibbs relation predicted by the random first order transition theory enabling us to deduce a scaling relation between the configurational entropy and the point-to-set length scale in these active systems. Our findings could be of great utility in conventional active systems such as self-propelled granules, Janus particles and dense bacterial suspensions, to mention a few.

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