论文标题

多功能$^7 $ lifepo $ _4 $在静水压力下的磁性特性

Magnetic Properties of Multifunctional $^7$LiFePO$_4$ under Hydrostatic Pressure

论文作者

Miniotaite, Ugne, Forslund, Ola Kenji, Nocerino, Elisabetta, Elson, Frank, Palm, Rasmus, Matsubara, Nami, Ge, Yuqing, Khasanov, Rustem, Kobayashi, Genki, Sassa, Yasmine, Weissenrieder, Jonas, Pomjakushin, Vladimir, Andreica, Daniel, Sugiyama, Jun, Månsson, Martin

论文摘要

LifePo $ _4 $(LFPO)是一种用于可充电锂离子电池的原型且知名的阴极材料。但是,其准二维(Q1D)结构与FE离子一起,LFPO还显示出有趣的低温磁性。我们的团队以前已经利用了MUON自旋旋转($μ^+$ SR)技术来研究LFPO中的磁性自旋顺序以及锂离子扩散。在这项初步研究中,我们扩展了调查,并利用高压$μ^+$ sr来研究对低$ t $磁性订单的影响。与理论预测相反,我们发现磁性排序温度以及有序的磁矩在高压(压缩应变)下增加。

LiFePO$_4$ (LFPO) is an archetypical and well-known cathode material for rechargeable Li-ion batteries. However, its quasi-one-dimensional (Q1D) structure along with the Fe ions, LFPO also displays interesting low-temperature magnetic properties. Our team has previously utilized the muon spin rotation ($μ^+$SR) technique to investigate both magnetic spin order as well as Li-ion diffusion in LFPO. In this initial study we extend our investigation and make use of high-pressure $μ^+$SR to investigate effects on the low-$T$ magnetic order. Contrary to theoretical predictions we find that the magnetic ordering temperature as well as the ordered magnetic moment increase at high pressure (compressive strain).

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